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Removal of Cu(II) ions from aqueous solution by activated carbon impregnated with humic acid

LIU Hanchao,FENG Suping,ZHANG Nannan,DU Xiaolin,LIU Yongli

《环境科学与工程前沿（英文）》 2014年第8卷第3期页码 329-336 doi: 10.1007/s11783-013-0553-9

摘要： Humic acid (HA) was impregnated onto powdered activated carbon to improve its Cu(II) adsorption capability. The optimum pH value for Cu(II) removal was 6. The maximum adsorption capacity of HA-impregnated activated carbon was up to 5.98 mg·g , which is five times the capacity of virgin activated carbon. The adsorption processes were rapid and accompanied by changes in pH. In using a linear method, it was determined that the equilibrium experimental data were better represented by the Langmuir isotherm than by the Freundlich isotherm. Surface charges and surface functional groups were studied through zeta potential and FTIR measurements to explain the mechanism behind the humic-acid modification that enhanced the Cu(II) adsorption capacity of activated carbon.

关键词： adsorption humic acid activated carbon heavy metal ions

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A ternary mechanism for the facilitated transfer of metal ions onto metal–organic frameworks: implications

《化学科学与工程前沿（英文）》页码 1632-1642 doi: 10.1007/s11705-022-2187-6

摘要： Although metal–organic frameworks offer a new platform for developing versatile sorption materials, yet coordinating the functionality, structure and component of these materials remains a great challenge. It depends on a comprehensive knowledge of a “real sorption mechanism”. Herein, a ternary mechanism for U(VI) uptake in metal–organic frameworks was reported. Analogous MIL-100s (Al, Fe, Cr) were prepared and studied for their ability to sequestrate U(VI) from aqueous solutions. As a result, MIL-100(Al) performed the best among the tested materials, and MIL-100(Cr) performed the worst. The nuclear magnetic resonance technique combined with energy-dispersive X-ray spectroscopy and zeta potential measurement reveal that U(VI) uptake in the three metal–organic frameworks involves different mechanisms. Specifically, hydrated uranyl ions form outer-sphere complexes in the surface of MIL-100s (Al, Fe) by exchanging with hydrogen ions of terminal hydroxyl groups (Al-OH₂, Fe-OH₂), and/or, hydrated uranyl ions are bound directly to Al(III) center in MIL-100(Al) through a strong inner-sphere coordination. For MIL-100(Cr), however, the U(VI) uptake is attributed to electrostatic attraction. Besides, the sorption mechanism is also pH and ionic strength dependent. The present study suggests that changing metal center of metal–organic frameworks and sorption conditions alters sorption mechanism, which helps to construct effective metal–organic frameworks-based sorbents for water purification.

关键词： U(VI) metal–organic frameworks adsorption mechanism metal node

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minimized fluorescent chemosensor array utilizing carboxylate-attached polythiophenes on a chip for metalions detection

Yui Sasaki, Xiaojun Lyu, Zhoujie Zhang, Tsuyoshi Minami

《化学科学与工程前沿（英文）》 2022年第16卷第1期页码 72-80 doi: 10.1007/s11705-021-2037-y

摘要： Chemosensor arrays have a great potential for on-site applications in real-world scenarios. However, to fabricate on chemosensor array a number of chemosensors are required to obtain various optical patterns for multi-analyte detection. Herein, we propose a minimized chemosensor array composed of only two types of carboxylate-functionalized polythiophene derivatives for the detection of eight types of metal ions. Upon recognition of the metal ions, the polythiophenes exhibited changes in their fluorescence intensity and various spectral shifts. Although both chemosensors have the same polymer backbone and recognition moiety, only the difference in the number of methylene groups contributed to the difference in the fluorescence response patterns. Consequently, the metal ions in aqueous media were successfully discriminated qualitatively and quantitatively by the chemosensor microarray on the glass chip. This study offers an approach for achieving a minimized chemosensor array just by changing the alkyl chain lengths without the necessity for many receptors and reporters.

关键词： metal ions polythiophene chemosensor array fluorescence pattern recognition

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Effects of metal ions on the morphology of calcium sulfate hemihydrate whiskers by hydrothermal method

Tianjie Liu, Hao Fan, Yanxia Xu, Xingfu Song, Jianguo Yu

《化学科学与工程前沿（英文）》 2017年第11卷第4期页码 545-553 doi: 10.1007/s11705-017-1665-8

摘要： The effects of Na , Mg , Al and Fe ion concentrations on the crystal morphology of calcium sulfate hemihydrate whiskers formed via a hydrothermal method have been studied. In the presence of Al concentrations higher than 1×10 mol/L the whiskers were significantly shorter and thicker and the presence of Mg and Fe resulted in shorter whiskers. The presence of Na did not affect the morphology of the whiskers. Through elemental analysis, it was determined that Mg and Al were selectively adsorbed on the surfaces of the crystals, whereas Fe underwent a hydrolysis reaction to form a brown precipitate which decreased the ion concentration in the solution. These results indicate that in raw materials used for the industrial preparation of calcium sulfate whiskers, Al and Fe should be removed and the Mg concentration should be less than 8 × 10 mol/L in order to obtain pure whiskers with high aspect ratios.

关键词： metal ions morphology calcium sulfate hemihydrate whiskers hydrothermal method selective adsorption

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Boron and nitrogen co-doped porous carbon derived from sodium alginate enhanced capacitive deionization for water purification

《化学科学与工程前沿（英文）》 2023年第17卷第12期页码 2014-2024 doi: 10.1007/s11705-023-2346-4

摘要： Capacitive deionization can alleviate water shortage and water environmental pollution, but performances are greatly determined by the electrochemical and desalination properties of its electrode materials. In this work, B and N co-doped porous carbon with micro-mesoporous structures is derived from sodium alginate by a carbonization, activation, and hydrothermal doping process, which exhibits large specific surface area (2587 m²·g^‒1) and high specific capacitance (190.7 F·g^‒1) for adsorption of salt ions and heavy metal ions. Furthermore, the materials provide a desalination capacity of 26.9 mg·g⁻¹ at 1.2 V in 500 mg·L^‒1 NaCl solution as well as a high removal capacity (239.6 mg·g^‒1) and adsorption rate (7.99 mg·g^‒1·min^‒1) for Pb²⁺ with an excellent cycle stability. This work can pave the way to design low-cost porous carbon with high-performances for removal of salt ions and heavy metal ions.

关键词： capacitance deionization porous carbon B/N co-doping heavy metal ions water purification

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基于纳米金/介孔NiO/泡沫镍纳米复合材料的微型电极用于地下水重金属检测 Article

薛博元, 杨倩, 夏楷东, 李志宏, 陈宇徽, 张大奕, 周小红

《工程（英文）》 2023年第27卷第8期页码 199-208 doi: 10.1016/j.eng.2022.06.005

摘要：

Heavy metals, notably Pb²⁺ and Cu²⁺, are some of the most persistent contaminants found in groundwater. Frequent monitoring of these metals, which relies on efficient, sensitive, cost-effective, and reliable methods, is a necessity. We present a nanocomposite-based miniaturized electrode for the concurrent measurement of Pb²⁺ and Cu²⁺ by exploiting the electroanalytical technique of square wave voltammetry. We also propose a facile in situ hydrothermal calcination method to directly grow binder-free mesoporous NiO on a three-dimensional nickel foam, which is then electrochemically seeded with gold nanoparticles (AuNPs). The meticulous design of a low-barrier Ohmic contact between mesoporous NiO and AuNPs facilitates target-mediated nanochannel-confined electron transfer within mesoporous NiO. As a result, the heavy metals Pb²⁺ (0.020 mg·L⁻¹ detection limit, 2.0–16.0 mg·L⁻¹detection range) and Cu²⁺ (0.013 mg·L⁻¹ detection limit, 0.4–12.8 mg·L⁻¹ detection range) can be detected simultaneously with high precision. Furthermore, other heavy metal ions and common interfering ions found in groundwater showed negligible impacts on the electrode's performance, and the recovery rate of groundwater samples varied between 96.3% ± 2.1% and 109.4% ± 0.6%. The compactness, flexible shape, low power consumption, and ability to remotely operate our electrode pave the way for onsite detection of heavy metals in groundwater, thereby demonstrating the potential to revolutionize the field of environmental monitoring.

关键词： AuNPs Mesoporous NiO Miniaturized electrode Heavy metal ions Groundwater Square wave voltammetry

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Removal of copper ions from aqueous solution by adsorption using LABORATORIES-modified bentonite (organo-bentonite

Sandy, Velycia MARAMIS, Alfin KURNIAWAN, Aning AYUCITRA, Jaka SUNARSO, Suryadi ISMADJI

《化学科学与工程前沿（英文）》 2012年第6卷第1期页码 58-66 doi: 10.1007/s11705-011-1160-6

摘要： Equilibrium, kinetic and thermodynamic aspects of the adsorption of copper ions from an aqueous solution using linear alkylbenzene sulfonate (LABORATORIES) modified bentonite (organo-bentonite) are reported. Modification of bentonite was performed via microwave heating with a concentration of LABORATORIES surfactant equivalent to 1.5 times that of the cation exchange capacity (CEC) of the raw bentonite. Experimental parameters affecting the adsorption process such as pH, contact time and temperature were studied. Several adsorption equations (e.g., Langmuir, Freundlich, Sips and Toth) with temperature dependency were used to correlate the equilibrium data. These models were evaluated based on the theoretical justifications of each isotherm parameter. The Sips model had the best fit for the adsorption of copper ions onto organo-bentonite. For the kinetic data, the pseudo-second order model was superior to the pseudo-first order model. Thermodynamically, the adsorption of copper ions occurs via chemisorption and the process is endothermic (Δ >0), irreversible (Δ >0) and nonspontaneous (Δ >0).

关键词： heavy metal copper adsorption organo-bentonite temperature dependent

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Fluoride ions adsorption from water by CaCO enhanced Mn–Fe mixed metal oxides

《化学科学与工程前沿（英文）》 2023年第17卷第2期页码 236-248 doi: 10.1007/s11705-022-2193-8

摘要： Novel CaCO₃-enhanced Mn–Fe mixed metal oxides (CMFC) were successfully prepared for the first time by a simple-green hydrothermal strategy without any surfactant or template combined with calcination process. These oxides were then employed as an adsorbent for adsorptive removal of excess fluoride ions. The adsorbent was characterized by SEM, XPS, XRD, FTIR, and BET analysis techniques. The adsorption property of CMFC toward fluoride ion was analyzed by batch experiments. In fact, CMFC exhibited adsorption capacity of 227.3 mg∙g^‒1 toward fluoride ion. Results showed that ion exchange, electrostatic attraction and chemical adsorption were the main mechanism for the adhesion of large amount of fluoride ion on the CMFC surface, and the high adsorption capacity responded to the low pH of the adsorption system. When the fluoride ion concentration was increased from 20 to 200 mg∙L^‒1, Langmuir model was more in line with experimental results. The change of fluoride ion adsorption with respect to time was accurately described by pseudo-second-order kinetics. After five cycles of use, the adsorbent still maintains a performance of 70.6% of efficiency, compared to the fresh adsorbent. Therefore, this material may act as a potential candidate for adsorbent with broad range of application prospects.

关键词： mesoporous materials metal oxides fluoride ion adsorption mechanism

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Recent progress in electrospun nanofibers and their applications in heavy metal wastewater treatment

《化学科学与工程前沿（英文）》 2023年第17卷第3期页码 249-275 doi: 10.1007/s11705-022-2245-0

摘要： Novel adsorbents with a simple preparation process and large capacity for removing highly toxic and nondegradable heavy metals from water have drawn the attention of researchers. Electrospun nanofiber membranes usually have the advantages of large specific surface areas and high porosity and allowing flexible control and easy functionalization. These membranes show remarkable application potential in the field of heavy metal wastewater treatment. In this paper, the electrospinning technologies, process types, and the structures and types of nanofibers that can be prepared are reviewed, and the relationships among process, structure and properties are discussed. On one hand, based on the different components of electrospun nanofibers, the use of organic, inorganic and organic−inorganic nanofiber membrane adsorbents in heavy metal wastewater treatment are introduced, and their advantages and future development are summarized and prospected. On the other hand, based on the microstructure and overall structure of the nanofiber membrane, the recent progresses of electrospun functional membranes for heavy metal removal are reviewed, and the advantages of different structures for applications are concluded. Overall, this study lays the foundation for future research aiming to provide more novel structured adsorbents.

关键词： electrospinning heavy metal adsorption nanostructure wastewater

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Strategies to manage the risk of heavy metal(loid) contamination in agricultural soils

Fang-Jie ZHAO

《农业科学与工程前沿（英文）》 2020年第7卷第3期页码 333-338 doi: 10.15302/J-FASE-2020335

摘要：

Soil contamination with heavy metal(loid)s threatens soil ecological functions, water quality and food safety; the latter is the focus of this review. Cadmium (Cd) and arsenic (As) are the toxic elements of most concern for food safety because they are relatively easily taken up by food crops. Rice is a major contributor of both Cd and As intakes to the Chinese population. Contamination and soil acidification are the main causes of high Cd levels in rice grains produced in some areas of southern China. The risk of Cd and As accumulation in food crops can be mitigated through agronomic practices and crop breeding. Liming is effective and economical at reducing Cd uptake by rice in acid soils. Paddy water management can produce opposite effects on Cd and As accumulation. Many genes controlling Cd and As uptake and translocation have been characterized, paving the way to breeding low accumulating crop cultivars through marker-assisted molecular breeding or genetic engineering. It is important to protect agricultural soils from future contamination. Long-term monitoring of anthropogenic additions and accumulation of heavy metal(loid)s in agricultural soils should be undertaken. Mass-balance models should be constructed to evaluate future trends of metal(loid)s in agricultural soils at a regional scale.

关键词： arsenic cadmium food safety heavy metals soil contamination

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Sulfur mediated heavy metal biogeochemical cycles in coastal wetlands: From sediments, rhizosphere to

《环境科学与工程前沿（英文）》 2022年第16卷第8期 doi: 10.1007/s11783-022-1523-x

摘要：

• In sediments, the transformation of sulfides may lead to the release of heavy metals.

关键词： Coastal wetland Heavy metal Sulfur Biogeochemical cycle

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Temporal variation of heavy metal pollution in urban stormwater runoff

Wen LI, Zhenyao SHEN, Tian TIAN, Ruimin LIU, Jiali QIU

《环境科学与工程前沿（英文）》 2012年第6卷第5期页码 692-700 doi: 10.1007/s11783-012-0444-5

摘要： Stormwater runoff from three types of urban surfaces, a parking lot, a street, and a building roof, was monitored during four rainfall events that occurred in the one-year period from June 2009 to June 2010. The event mean concentrations (EMC) of dissolved copper (Cu), lead (Pb), zinc (Zn), manganese (Mn), and iron (Fe) exceeded China’s National Water Quality Standards for Surface Water. The degree of heavy metal contamination was related to the type of underlying surfaces. Additionally, the concentration of dissolved heavy metals peaked shortly after the runoff began and then declined sharply as a result of adequate flushing. First flush effects of varying degrees were also observed during all of the monitored rainfall events based on the first flush ratio ( ). Redundancy analysis revealed that four environmental variables (rainfall depth, intensity, antecedent dry weather period and type of underlying surface) had significant effects on the strengths of the first flush effects, accounting for 72.9% of the variation in the . Dissolved metals presented varying first flush effects on different underlying surfaces that occurred in the following relative order: parking lot>roof>road for low intensity and high runoff volume rainfall events; parking lot>road>roof for high intensity and low runoff volume events. The relative strength of the first flush for dissolved heavy metals was Fe, Mn>Cu, Zn>Pb.

关键词： urban stormwater heavy metal pollution temporal variation event mean concentration first flush effect redundancy analysis

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Reuse of heavy metal-accumulating

Dongdong MA,Hongwen GAO

《环境科学与工程前沿（英文）》 2014年第8卷第6期页码 952-959 doi: 10.1007/s11783-013-0619-8

摘要： Phytoremediation technology is regarded as a simple and efficient way to remove heavy metals from contaminated soil. A reasonable disposal of metal hyperaccumulators is always a major issue in waste reuse and resource-saving. The heavy metal-accumulating (L.) was investigated where heavy metals were desorbed by a facile acid-treatment. The result indicated that more than 90% of heavy metals (Zn, Pb and Cu) was extracted from with 0.2 mmol·L HCl. The plant residue was used to adsorb heavy metals ions. The adsorption fitted the Langmuir isotherm model with the saturation adsorption capacity of 9.5 mg·g Zn , 36.2 mg·g Pb and 12.9 mg·g Cu , and the surface complexation and the backfilling of heavy metal-imprinting cavities existed simultaneously during the adsorption. The treatment of wastewaters indicated that the plant residue exhibited a high removal rate of 97% for Cu. Also, the material could be recycled. The method offers a new disposal approach for heavy metal hyperaccumulator.

关键词： heavy metals Cynondon dactylon acid-treatment adsorption recycling

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Interactions between metal ions and the biopolymer in activated sludge: quantification and effects of

Yun Zhou, Siqing Xia, Binh T. Nguyen, Min Long, Jiao Zhang, Zhiqiang Zhang

《环境科学与工程前沿（英文）》 2017年第11卷第1期 doi: 10.1007/s11783-017-0898-6

摘要： The biopolymer showed two protein-like fluorescence peaks (peaks A and B). Interactions of Pb(II) and biopolymer were quantified at various system pH values. System pH values significantly affect the quenching constant values for both peaks. Peak B plays a more important role in the interactions than peak A. Removal mechanism of metal ions by activated sludge system was further disclosed. The quantification and effects of system pH value on the interactions between Pb(II) and the biopolymer from activated sludge were investigated. The biopolymer had two protein-like fluorescence peaks (Ex/Em= 280 nm/326–338 nm for peak A; Ex/Em= 220–230 nm/324–338 nm for peak B). The fluorescence intensities of peak B were higher than those of peak A. The fluorophores of both peaks could be largely quenched by Pb(II), and the quencher dose for peak B was about half of that for peak A. The modified Stern-Volmer equation well depicted the fluorescence quenching titration. The quenching constant (Ka) values for both peaks decreased with rising system pH value, and then sharply decreased under alkaline conditions. It could be attributed to that the alkaline conditions caused the reduction of available Pb(II) due to the occurrence of Pb(OH)2 sediments. The Ka values of peak B were bigger than those for peak A at the same system pH values. Accordingly, the aromatic protein (peak B) plays the key role in the interactions between metal ions and the biopolymer.

关键词： Metal ions Biopolymer Activated sludge Three-dimensional excitation emission matrix (3D-EEM) Fluorescence regional integration (FRI) technique Quantification

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胶束强化超滤技术在重金属废水处理中的研究进展

姚青旭,贾铭椿,王晓伟

《中国工程科学》 2014年第16卷第7期页码 95-99

摘要：

胶束强化超滤技术（MEUF）作为一种新兴的水处理技术，在重金属废水净化方面有着较好的应用前景。本文通过总结前人的研究结果，综合讨论了影响金属离子截留效果的各个因素，为优化MEUF提出了一些建议。并就当前采用胶束强化超滤法处理金属离子技术的最新发展与表面活性剂的循环再利用作了简要的介绍。

关键词：胶束强化超滤表面活性剂临界浓度

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标题作者时间类型操作

Removal of Cu(II) ions from aqueous solution by activated carbon impregnated with humic acid

LIU Hanchao,FENG Suping,ZHANG Nannan,DU Xiaolin,LIU Yongli

期刊论文

A ternary mechanism for the facilitated transfer of metal ions onto metal–organic frameworks: implications

期刊论文

minimized fluorescent chemosensor array utilizing carboxylate-attached polythiophenes on a chip for metalions detection

Yui Sasaki, Xiaojun Lyu, Zhoujie Zhang, Tsuyoshi Minami

期刊论文

Effects of metal ions on the morphology of calcium sulfate hemihydrate whiskers by hydrothermal method

Tianjie Liu, Hao Fan, Yanxia Xu, Xingfu Song, Jianguo Yu

期刊论文

Boron and nitrogen co-doped porous carbon derived from sodium alginate enhanced capacitive deionization for water purification

期刊论文

基于纳米金/介孔NiO/泡沫镍纳米复合材料的微型电极用于地下水重金属检测

薛博元, 杨倩, 夏楷东, 李志宏, 陈宇徽, 张大奕, 周小红

期刊论文

Removal of copper ions from aqueous solution by adsorption using LABORATORIES-modified bentonite (organo-bentonite

Sandy, Velycia MARAMIS, Alfin KURNIAWAN, Aning AYUCITRA, Jaka SUNARSO, Suryadi ISMADJI

期刊论文

Fluoride ions adsorption from water by CaCO enhanced Mn–Fe mixed metal oxides

期刊论文

Recent progress in electrospun nanofibers and their applications in heavy metal wastewater treatment

期刊论文

Strategies to manage the risk of heavy metal(loid) contamination in agricultural soils

Fang-Jie ZHAO

期刊论文

Sulfur mediated heavy metal biogeochemical cycles in coastal wetlands: From sediments, rhizosphere to

期刊论文

Temporal variation of heavy metal pollution in urban stormwater runoff

Wen LI, Zhenyao SHEN, Tian TIAN, Ruimin LIU, Jiali QIU

期刊论文

Reuse of heavy metal-accumulating

Dongdong MA,Hongwen GAO

期刊论文

Interactions between metal ions and the biopolymer in activated sludge: quantification and effects of

Yun Zhou, Siqing Xia, Binh T. Nguyen, Min Long, Jiao Zhang, Zhiqiang Zhang

期刊论文

胶束强化超滤技术在重金属废水处理中的研究进展

姚青旭,贾铭椿,王晓伟

期刊论文

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